Electro-enhanced removal of cobalt ions from aqueous solution by capacitive deionization

Electro-enhanced removal of cobalt (Co) ions from aqueous solution by capacitive deionization (CDI) was investigated in this study. The effect of applied voltage and initial Co ions concentration, as well as coexisted ions on removal efficiency of Co ions was determined. Co ions adsorption performance was also evaluated by kinetic models, isotherm models and three mass transfer models. The results indicated that the removal efficiency of Co ions had positive correlation with applied voltage (R² = 0.9991), which increased from 15.11% to 36.54% when the applied voltage increased from 0 V to 1.2 V. However, the removal efficiency of Co ions decreased gradually from 36.54% to 9.51% with the increasing initial Co ions concentration from 5 to 30 mg L^-1. The coexisted ions (Sr and Cs) also largely inhibited the removal efficiency of Co ions and make it reduce to 8.37%. After fitting the adsorption data, pseudo-second order (PSO) model was better than pseudo-first order (PFO) for each applied voltage and initial concentration. A monolayer adsorption is the main adsorption mechanism of Co ions adsorption on the activated carbon cloth (ACC) because of the higher regression coefficient (0.964) by Langmuir isotherm. Based on kinetics together with the equilibrium isotherm, three mass transfer models were established and adsorption of the ions onto the active sites (AAS) model is the rate-limiting step due to the best fitting for the kinetic adsorption data of Co ions on ACC electrode. In addition, the Co ions were uniformly distributed on ACC electrode after adsorption.