Mechanical activation to enhance the natural floatability of waste printed circuit boards

The metal in the waste printed circuit boards (WPCBs) is an excellent secondary metal resource. WPCBs were ground to dissociate, and impurities in the dissociated product were removed by gradient flotation to recover valuable metals in this study. The effects of crushing methods on size composition and dissociation state of the crushed products were studied. Then the gradient flotation experiment was designed to verify the natural floatability of ground materials. Grinding test shows that impact crushing has greater grinding fineness (-0.074 mm) than shear crushing, which is 42.14% and 26.18% respectively with 5 min grinding. The flotation test results illustrate that the natural floatability of impurities increases with the grinding fineness, that is, the yield of floats increases without flotation reagents. For impact crushing and shear crushing, the floats yields are 38.48% and 31.75% respectively, accompanied by 70.53% and 65.46% impurity removal for ground materials with 5 min grinding. Subsequently, 21.61% and 26.35% of impurities can be further removed with the aid of collector. Finally, the recovery of Cu in concentrate reaches 67.84% and 65.75%, respectively. FT-IR proves that the excellent floatability of particles is caused by the significant hydrophobic group. Mechanical grinding has been proved to have double effects of improving dissociation and natural floatability.