Humidity impedimetric sensor based on vanadium pentoxide xerogel modified screen-printed graphite electrochemical
Maria G Trachioti1, Mamas I Prodromidis1
1Department of Chemistry, University of Ioannina, 45 110, Ioannina, Greece.
Talanta
|May 28, 2020
Summary
A new vanadium pentoxide xerogel (VPX) humidity sensor was developed on a screen-printed electrochemical cell. This VPX sensor offers high sensitivity and fast response for real-time relative humidity monitoring.
Area of Science:
- Materials Science
- Electrochemistry
- Sensor Technology
Background:
- Development of advanced materials for environmental monitoring.
- Need for sensitive and stable relative humidity sensors.
Purpose of the Study:
- To design and characterize a novel humidity sensor.
- To utilize vanadium pentoxide xerogel (VPX) on a screen-printed electrochemical cell (SPC) for relative humidity (RH%) sensing.
Main Methods:
- Fabrication of VPX thin films on SPC.
- Characterization using scanning electron microscopy (SEM), ATR-infrared spectroscopy, and electrochemical impedance spectroscopy (EIS).
- Performance evaluation across a wide RH range (10-93%).
Main Results:
- VPX/SPC sensor demonstrated high sensitivity (190-500 Ohm/RH%) and a wide RH detection range.
- Achieved a sensor response of 93% with low hysteresis and good storage stability.
- Fast response (52 s) and recovery (21 s) times were recorded.
- EIS data provided insights into the conduction mechanism and interface properties.
Conclusions:
- The VPX-based sensor is suitable for on-site and real-time relative humidity monitoring.
- The developed sensor exhibits promising performance characteristics for ambient condition applications.
Related Concept Videos
Potentiometry: Membrane Electrodes
1.4K
Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at...
1.4K
Amperometry: Overview
1.4K
Amperometry is a technique commonly used to measure the concentration of specific analytes in a solution by monitoring the electric current generated during an electrochemical reaction. It involves applying a constant potential between a working electrode and a reference electrode to measure the resulting current, which is proportional to the concentration of the analyte. The Clark oxygen electrode operates based on this principle of amperometry. It consists of a cathode and an anode enclosed...
1.4K
Voltammetry: Overview
2.7K
Voltammetry is an electroanalytical technique in which the current flowing through an electrochemical cell is measured as a function of applied potential, typically under conditions of concentration polarization. The technique provides valuable information about redox-active species, and the current response is plotted as a voltammogram.
A voltammetric cell uses three electrodes: a working electrode, a reference electrode, and an auxiliary electrode. The redox reactions occur in the working...
A voltammetric cell uses three electrodes: a working electrode, a reference electrode, and an auxiliary electrode. The redox reactions occur in the working...
2.7K
Potentiometry: Types of Electrodes
1.7K
Reference electrodes serve as a stable reference point for potentiometric measurements, while indicator and working electrodes react to variations in the composition of a solution.
The Standard Hydrogen Electrode (SHE) is a widely used reference electrode that maintains zero potential across all temperatures. However, its need for a continuous hydrogen gas supply renders it impractical for everyday use.
An alternative to SHE is the Saturated Calomel Electrode (SCE). This electrode features an...
The Standard Hydrogen Electrode (SHE) is a widely used reference electrode that maintains zero potential across all temperatures. However, its need for a continuous hydrogen gas supply renders it impractical for everyday use.
An alternative to SHE is the Saturated Calomel Electrode (SCE). This electrode features an...
1.7K


