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Updated: Dec 20, 2025
High-Contrast and Fast Photorheological Switching of a Twist-Bend Nematic Liquid Crystal
Published on: October 31, 2019
Reversible Light-Responsive Solventless-Liquid Switch: Polarization-Induced Dynamic Surface Ordering-Disordering in
Lopamudra Bhattacharjee1, Kallol Mohanta1, Sudip K Batabyal2
1Nanotech Research Innovation and Incubation Center, PSG Institute of Advanced Studies, Avinashi Road, Peelamedu, Coimbatore 641004, Tamil Nadu, India.
Abstract:
Naturally stimulated dynamic ordering-disordering of biomolecules via noncovalent interactions is a commonly occurring phenomenon in biological systems. Herein, we report the effect of induced polarization on the charge carrier dynamics of carbon-quantum-dot-based nano ionic materials (CQD-NIMs) under simulated solar radiation. The solventless liquid-like CQD-NIMs is composed of polystyrenesulfonate (PSS)-passivated CQD as the core-corona system with a polyetheramine (Jeffamine) forming the canopy. The material was observed to behave as a dielectric when placed between two electrodes. Dynamic ordering-disordering of the corona around the CQD surface under induced polarization allowed excess current flow through the solventless material when exposed to simulated solar radiation. Such reversible molecular-assembly-induced photoconducting behavior of the CQDs was characterized with impedance spectroscopy and steady state fluorescence spectroscopy. The concept depicted in the present manuscript may be further developed to design smart light-sensitive molecular switching devices.
