Oxidation of NO Using Hydrogen Peroxide Vapor over Mo/TiO₂

xMo/TiO₂ catalysts (x = 1, 2, 3, and 4%) were prepared using the coprecipitation method in the present study. The coprecipitation method was used in the thermal catalytic decomposition of H₂O₂ steam to treat NO at a low temperature range (80-160 °C). Several characterization techniques have been employed, such as X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller measurements, transmission electron microscopy (TEM), scanning electron microscopy and energy-dispersive X-ray spectrometry (SEM-EDXS), and Fourier transform infrared spectroscopy. The activity tests showed that the incorporation of molybdenum into TiO₂ led to a significant increase in the catalytic oxidation of NO, and under the condition of H₂O₂/NO = 6:1 (molar ratio), the NO removal rate of 2% Mo/TiO₂ is the highest, reaching 92.56%. XRD, TEM, and SEM-EDXS analyses showed that Mo was well dispersed on the surface of an anatase-phase TiO₂. XPS analysis indicated that Mo mixed with slag mainly existed in the form of Mo⁶⁺. Moreover, in comparison with the mostly reported SCO catalysts, used for the elimination of NO, the prepared Mo/TiO₂ catalyst showed excellent stability and sulfur resistance.