Vacancy Occupation-Driven Polymorphic Transformation in Cobalt Ditelluride for Boosted Oxygen Evolution Reaction

Transition-metal dichalcogenides (TMDs) hold great potential as an advanced electrocatalyst for oxygen evolution reaction (OER), but to date the activity of transition metal telluride catalysts are demonstrated to be poor for this reaction. In this study, we report the activation of CoTe₂ for OER by doping secondary anions into Te vacancies to trigger a structural transition from the hexagonal to the orthorhombic phase. The achieved orthorhombic CoTe₂ with partial vacancies occupied by P-doping exhibits an exceptional OER catalytic activity with an overpotential of only 241 mV at 10 mA cm^-2 and a robust stability more than 24 h. The combined experimental and theoretical studies suggest that the defective phase transformation is controllable and allows the synergism of vacancy, doping as well as the reconstructed crystallographic structure, ensuring more exposure of catalytic active sites, rapid charge transfer, and energetically favorable intermediates. This vacancy occupation-driven strategy of structural transformation can also be manipulated by S- and Se-doping, which may offer useful guidance for developing tellurides-based electrocatalyst for OER.