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Ørsted and Bunsen: Voltaic Batteries, Electric Arcs, Electromagnetism, and Electrolysis
1School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, Queensland, 4072, Australia.
Abstract:
200 years ago Ørsted laid the foundation of electromagnetism in his famous experiment in which a magnetic needle is deflected in the electrical field of a platinum wire. For this he used his own Cu-Zn trough battery, which was among the best then available, but 21 years later it was surpassed by the coal-zinc battery invented by Bunsen, which became highly successful and acclaimed. That year, 1841, Bunsen made his first direct contact with Scandinavia when he visited Berzelius in Stockholm, Palmstedt in Gothenburg, and Ørsted, Scharling, and Zeise in Copenhagen. Like almost everybody in continental Europe, they adopted Bunsen's battery, and Ørsted used it for his experiments with a very large electromagnet. The paths of Ørsted's and Bunsen's research crossed again much later through the synthesis of elemental aluminum, which was first achieved by Ørsted in 1825 (although it was probably not obtained as the pure metal) and performed quite differently by Bunsen, by electrolysis using his coal-zinc battery, in 1854.
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