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The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...
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Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
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Ziegler–Natta polymerization is another form of addition or chain‐growth polymerization used for synthesizing linear polymers over branched polymers. The catalyst used for polymerization is the Ziegler–Natta catalyst, named after Karl Ziegler and Giulio Natta, who developed it in 1953. This catalyst is an organometallic complex of titanium tetrachloride and triethyl aluminum, with the active form of the catalyst being an alkyl titanium compound. Using the Ziegler–Natta...
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Functional Zwitterionic Polymers on Surface: Structures and Applications.

Minglun Li1, Bilin Zhuang2, Jing Yu1

  • 1School of Materials Science and Engineering, Nanyang Technological University, Singapore, 639798, Singapore.

Chemistry, an Asian Journal
|June 8, 2020
PubMed
Summary
This summary is machine-generated.

Zwitterionic polymers, with balanced charges, offer unique properties like hydration and temperature response. This review explores their surface applications in coatings, solutions, and hydrogels, including simulation insights.

Keywords:
functional polymer surfaceshydrogelszwitterionic polymers

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Area of Science:

  • Polymer Chemistry
  • Materials Science
  • Surface Science

Background:

  • Zwitterionic polymers possess both anionic and cationic groups.
  • These polymers exhibit unique functionalities such as strong hydration and temperature responsiveness.
  • Their applications span industrial, biological, and medical fields.

Purpose of the Study:

  • To review the structures and surface applications of functional zwitterionic polymers.
  • To categorize applications based on polymeric system architecture: surface coating, complex solutions, and hydrogels.
  • To discuss simulation and theoretical work and suggest future development directions.

Main Methods:

  • Literature review focusing on zwitterionic polymer structures and surface applications.
  • Categorization of applications into surface coating, complex solutions, and hydrogels.
  • Analysis of simulation and theory studies related to zwitterionic polymers.

Main Results:

  • Zwitterionic polymers demonstrate significant potential in surface modification across various architectures.
  • Applications include advanced coatings, stable complex solutions, and functional hydrogels.
  • Simulation and theory provide insights into the behavior and design of these polymers.

Conclusions:

  • Zwitterionic polymers are versatile materials for surface-based applications.
  • Further research in simulation and theory can drive innovation in zwitterionic polymer design.
  • The unique properties of zwitterionic polymers position them for continued growth in diverse fields.