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Updated: Dec 19, 2025

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
Published on: October 18, 2019
Pt(0)-Catalysed synthesis of new bifunctional silanes
Rafał Januszewski1, Michał Dutkiewicz, Adrian Franczyk
1Faculty of Chemistry, Adam Mickiewicz University in Poznań, Uniwersytetu Poznańskiego 8, 61-614, Poznan, Poland. r.janusz@amu.edu.pl.
Abstract:
We report herein very efficient syntheses of new functional silanes obtained via olefin hydrosilylation. New bifunctional compounds contain attractive functional groups such as epoxy, fluoroalkyl, trisilylamine, chloropropyl, and methacroiloxy which can play different roles in molecular systems. Moreover, the catalytic system proposed by us exhibits high selectivity and tolerance to a wide range of functional groups. It also permitted obtaining total conversions of the starting reagents in a relatively short time under mild conditions.
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