Recent Progress in Electrolytes for Zn-Air Batteries

Zn-air battery is considered as one of the most promising candidates for next-generation batteries for energy storage due to safety, high energy density, and low cost. There are many challenges in electrolytes for developing high-performance rechargeable Zn-air cells as well as electrocatalysts. An electrolyte is the crucial part of the rechargeable Zn-air batteries that determine their capacity, cycling stability, and lifetime. This paper reviews the most recent progress in designing and fabricating electrolytes in aqueous and flexible Zn-air batteries. The discussion on the surface reaction relationships was covered between air-catalyst-electrolyte and electrolyte-zinc reaction mechanism. We highlight the recent developments of three different electrolytes in zinc-air battery: aqueous electrolyte, room temperature ionic liquid, and quasi-solid flexible electrolyte. Furthermore, the general perspective is proposed for designing and fabricating electrolytes to improve the performance and prolong the lifetime of Zn-air batteries.