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Related Experiment Video

Updated: Dec 18, 2025

Quantification of Hydrogen Concentrations in Surface and Interface Layers and Bulk Materials through Depth Profiling with Nuclear Reaction Analysis
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Quantification of Hydrogen Concentrations in Surface and Interface Layers and Bulk Materials through Depth Profiling with Nuclear Reaction Analysis

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Origin of micrometer-scale dislocation motion during hydrogen desorption.

Motomichi Koyama1, Seyedeh Mohadeseh Taheri-Mousavi2,3, Haoxue Yan2

  • 1Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan.

Science Advances
|June 18, 2020
PubMed
Summary

Hydrogen desorption causes dislocation movement in high-strength metals. Grain boundary hydrogen segregation induces stresses, explaining hydrogen embrittlement mechanisms and informing future research.

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Area of Science:

  • Materials Science
  • Metallurgy
  • Hydrogen Embrittlement

Background:

  • Hydrogen is a key energy carrier but causes significant embrittlement in high-strength metals.
  • Understanding hydrogen-defect interactions is crucial for mitigating this issue.

Purpose of the Study:

  • To investigate the mechanisms of hydrogen-induced embrittlement in metals.
  • To elucidate the role of hydrogen-defect interactions in material failure.

Main Methods:

  • In situ electron channeling contrast imaging under no external stress.
  • Molecular dynamics simulations.
  • Grand canonical Monte Carlo simulations.

Main Results:

  • Dislocations moved up to 1.5 μm during hydrogen desorption.
  • Grain boundary hydrogen segregation was found to induce long-range shear stresses and short-range atomic stress fluctuations.

Conclusions:

  • Hydrogen desorption can drive significant dislocation motion.
  • Grain boundary hydrogen segregation is a critical factor in hydrogen embrittlement.
  • These segregation effects must be widely considered in hydrogen research.