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Updated: Dec 18, 2025

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Trisubstituted geminal diazaalkene derived transient 1,2-carbodications

Debdeep Mandal1, Felix Stein, Shubhadeep Chandra

  • 1Tata Institute of Fundamental Research Hyderabad, Gopanpally, Hyderabad 500107, Telangana, India. ajana@tifrh.res.in.

Chemical Communications (Cambridge, England)
|June 20, 2020
PubMed
Summary

Transient 1,2-carbodications with a hydrogen substituent exhibit reduced charge repulsion through intramolecular base-coordination. This study explores charge delocalization in these novel carbocation species using N-heterocyclic olefins.

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