Design and performance of a novel direct Z-scheme NiGa₂O₄/CeO₂ nanocomposite with enhanced sonocatalytic activity

A novel direct Z-scheme NiGa₂O₄/CeO₂ nanocomposite was designed and prepared via simple sol-hydrothermal and calcination methods, and its sonocatalytic activity was tested by studying the degradation of a model antimicrobial agent, malachite green (MG), under ultrasonic irradiation. Near complete (96.2%) degradation of MG (at 10 mg/L) could be achieved by the NiGa₂O₄/CeO₂ nanocomposite (at 1.0 g/L) after ultrasonic irradiation (40 kHz, 300 W) for 60 min at 25 °C. Under the same conditions, only 51.2 and 72.0% of the MG degraded in the presence of NiGa₂O₄ and CeO₂ (at 1.0 g/L), respectively. These results demonstrate that the direct Z-scheme NiGa₂O₄/CeO₂ nanocomposite has excellent sonocatalytic activity, which is attributed to the matching band-gaps between NiGa₂O₄ and CeO₂. The sonocatalytic activity of NiGa₂O₄/CeO₂ nanocomposite decreased by 17% after four cycles of reuse, which is indicative of relatively good reusability. Scavenging experiments revealed that sonocatalytic degradation of MG results from the combined action of hydroxyl radicals (OH) and holes (h⁺), with the latter having a greater contribution. The pathways and mechanism of MG degradation were proposed based on the degradation intermediates detected. The results demonstrate that the prepared direct Z-scheme NiGa₂O₄/CeO₂ nanocomposite worked as designed and exhibited high and stable sonocatalytic activity during MG degradation, and could thus serve as a promising candidate in sonocatalytic treatment of other organic pollutants in wastewaters. The findings also provide new insights on the mechanism of sonocatalytic degradation and the design of efficient Z-scheme sonocatalysts.