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Supercritical Nitrogen Processing for the Purification of Reactive Porous Materials
Published on: May 15, 2015
A study of the desulfurization selectivity of a reductive and extractive desulfurization process with sodium
Xianglong Meng1, Pin Zhou1, Lu Li1
1School of Environmental Science and Engineering, Shanghai Jiao Tong University, Dongchuan Road 800, Shanghai, 200240, China.
Abstract:
The selectivity of a facile reductive and extractive desulfurization process was studied. In this desulfurization method, polyethylene glycol was used as the extractant, and sodium borohydride was used as the reductant. Several different simulated fuels were prepared by dissolving thiophenic sulfides, methylbenzene and hexylene in octane. The results showed that methylbenzene and olefins had different effects on different sulfur compounds during this desulfurization process. The extraction and reduction mechanisms were also explained. Four factors could affect the desulfurization performance: (1) intermolecular hydrogen bonding: (a) active O bonding with aromatic H or (b) S bonding with H atoms in hydroxide radicals, (2) "like-dissolves-like" interactions between polyethylene glycol and thiophenic sulfides, (3) the methyl steric hindrance effect and the electron density of sulfur atoms, and (4) the combination of S atoms with produced nickel boride to form active desulfurization centres. The desulfurization reaction path was also deduced according to the GC/MS results.
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