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Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction

Kentaro Fuku1, Momoka Miyata, Shinya Takaishi

  • 1Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Sendai 980-8578, Japan. h-iguchi@tohoku.ac.jp.

Chemical Communications (Cambridge, England)
|July 2, 2020
PubMed

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The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...
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