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Transport and thermodynamics in quantum junctions: A scattering approach
Alexander Semenov1, Abraham Nitzan1
1Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA.
The Journal of Chemical Physics
|July 3, 2020
Summary
We developed a scattering approach for quantum transport and thermodynamics. This method accurately models systems strongly coupled to thermal environments, yielding new insights into non-equilibrium steady states and energy dissipation.
Area of Science:
- Quantum physics
- Condensed matter physics
- Thermodynamics
Background:
- Standard non-equilibrium Green's function methods are used for quantum transport.
- Recent studies explored quantum thermodynamics in slowly driven systems.
- Understanding quantum systems coupled to multiple thermal environments is crucial.
Purpose of the Study:
- To present a novel scattering approach for quantum transport and thermodynamics.
- To extend existing formalisms to systems with multiple thermal baths and strong coupling.
- To derive new expressions for non-equilibrium steady states and energy dissipation.
Main Methods:
- Developed a scattering approach based on quantum system-environment interactions.
- Derived general expressions for the non-equilibrium steady-state density matrix.
- Obtained a general expression for dissipated power for driven systems without wide-band approximation.
- Validated the symmetric splitting of system-bath interactions for multiple baths.
- Demonstrated equivalence to Landauer-Buttiker formalism and its extensions.
Main Results:
- Derived a general explicit expression for the non-equilibrium steady-state density matrix for multi-bath systems.
- Obtained a general expression for dissipated power for a driven resonant level, considering changing energy levels and couplings.
- Confirmed the validity of symmetric splitting for multi-bath interactions.
- Showed the equivalence of the scattering approach to established transport formalisms.
- Generalized entropy production expressions to multi-bath driven systems.
Conclusions:
- The scattering approach provides a unified framework for quantum transport and thermodynamics.
- The method accurately describes systems under strong coupling to multiple thermal environments.
- New results offer deeper understanding of non-equilibrium phenomena and energy dissipation in quantum systems.
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