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Updated: Dec 15, 2025

Photochemical Oxidative Growth of Iridium Oxide Nanoparticles on CdSe@CdS Nanorods
Published on: February 11, 2016
Enhancing the activity of photocatalytic hydrogen evolution from CdSe quantum dots with a polyoxovanadate cluster
Emily H Edwards1, Alex A Fertig, Kevin P McClelland
1Department of Chemistry, University of Rochester, Rochester, New York 14627, USA. krauss@chem.rochester.edu bren@chem.rochester.edu matson@chem.rochester.edu.
Abstract:
We report the improvement of photocatalytic proton reduction using molecular polyoxovanadate-alkoxide clusters as hole scavengers for CdSe quantum dots. The increased hydrogen production is explained by favorable charge interactions between reduced forms of the cluster and the charge on the quantum dots arising from the capping ligands.
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