Core-Shell Nanohydrogels with Programmable Swelling for Conformance Control in Porous Media
Liyuan Zhang1, Alireza Abbaspourrad2, Shima Parsa1
1School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138, United States.
ACS Applied Materials & Interfaces
|July 8, 2020
Summary
Core-shell nanohydrogels with delayed swelling effectively control fluid flow in oil reservoirs. These nanohydrogels block high-permeability zones, redirecting water to enhance oil recovery and improve sweep efficiency.
Area of Science:
- Petroleum Engineering
- Materials Science
- Chemical Engineering
Background:
- Conformance control in waterflooding enhances oil production by redistributing water flow.
- Preformed gel particles redirect flow but face limitations in reservoir penetration and shear stability.
- Nanoscale materials offer potential for improved deep reservoir conformance control.
Purpose of the Study:
- To develop and evaluate core-shell nanohydrogels with delayed swelling for enhanced oil recovery.
- To investigate the flow diversion capabilities of these nanohydrogels in porous media.
- To assess their potential as conformance control agents in oil reservoirs.
Main Methods:
- Fabrication of core-shell nanohydrogels with controlled delayed swelling behavior.
- Microfluidic experiments using a 3D porous medium micromodel with confocal microscopy visualization.
- Core flood experiments to evaluate permeability reduction and flow diversion in reservoir samples.
Main Results:
- Nanohydrogels exhibited a 200-fold volume increase after 30 days under reservoir conditions.
- Swollen nanohydrogels reduced micromodel permeability and diverted flow to low-permeability regions.
- Core flood experiments confirmed significant permeability reduction and fluid flow diversion.
Conclusions:
- Core-shell nanohydrogels demonstrate effective flow control in porous media.
- Delayed swelling behavior allows for deeper reservoir penetration and targeted conformance control.
- These nanohydrogels show promise as advanced conformance control agents for oil recovery.


