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Published on: December 20, 2016
One water to bind a chloride-chloride ion pair: isolation of discrete [Cl2(H2O)]2- in the solid state
Owen J Curnow1, Rathiga Senthooran
1School of Physical and Chemical Sciences, University of Canterbury, Private Bag 4800, Christchurch 8140, New Zealand. owen.curnow@canterbury.ac.nz.
Abstract:
A discrete dichloride ion pair in the form of a monohydrate, [Cl2(H2O)]2-, was isolated using the triaminocyclopropenium cation [C3(NHex2)(N(CH2CF3)2)2]+. Although this ion pair is calculated to be unstable in the gas phase, the ionic lattice and weak CH-Cl hydrogen bonds assist the stabilization of the cluster. The D2O and HDO isotopomers were also prepared and characterized.
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