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Updated: Dec 14, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Quantitative Rotational to Librational Transition in Dense H2 and D2

Miriam Peña-Alvarez1, Veronika Afonina1, Philip Dalladay-Simpson2

  • 1Centre for Science at Extreme Conditions & The School of Physics and Astronomy, The University of Edinburgh, Peter Guthrie Tait Road, Edinburgh, EH9 3FD, U.K.

The Journal of Physical Chemistry Letters
|July 18, 2020
PubMed
Summary

Solid hydrogen and deuterium spectra change dramatically under pressure, losing quantum properties. They transform from quantum rotors to harmonic oscillators, explained by a single inhibited rotor model.

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