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Longitudinal shape evolution of Ag2S nanoparticles from nanospheres, rhombic dodecahedrons, nanorods, to nanocubes
Hyunmi Doh1, Wonseok Lee, Yunmo Sung
1Department of Chemistry, Pohang University of Science and Technology, Cheongam-ro 77, Nam-Gu, Pohang, 37673, South Korea. sungjee@postech.ac.kr.
Abstract:
Longitudinal shape evolution of Ag2S nanoparticles is reported. Initially 9 nm nanospheres turn into faceted rhombic dodecahedrons and elongate to minimize surface energy. The elongated rhombic dodecahedrons show oriented attachments to 〈-104〉 directions sequentially yielding dimers, linear oligomers, and nanorods. Lateral sides of nanorods fuse to thermodynamically stable nanocubes upon ripening.
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