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Updated: Dec 14, 2025
From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
Published on: March 24, 2018
O-I-O halogen bond of halonium ions
Sofia Lindblad1, Flóra Boróka Németh, Tamás Földes
1Department of Chemistry - BMC, Uppsala University, SE-751 23 Uppsala, Sweden. mate.erdelyi@kemi.uu.se.
Abstract:
The reactivity of halonium ions is conveniently modulated by three-center, four-electron halogen bonds. Such stabilized halonium complexes are valuable reagents for oxidations and halofunctionalization reactions. We report the first example of the stabilization of a halenium ion in a three-center, four-electron halogen bond with two oxygen ligands. The influence of electron density and solvent on the stability of the complexes is assessed. O-I-O halogen bond complexes are applicable as synthetic reagents and as supramolecular synthons.
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