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Related Experiment Videos

[N,N-bis(2-hydroxyethyl)dithiocarbamato-S,S']dichlorogold( II).

C J Lock1, M A Turner, R V Parish

  • 1Department of Chemistry, McMaster University, Hamilton, ON, Canada.

Acta Crystallographica. Section C, Crystal Structure Communications
|December 15, 1988
PubMed
Summary

This study details the crystal structure of a novel gold(III) dithiocarbamate complex. The gold atom exhibits a distorted square planar geometry, forming linear chains in the crystal lattice.

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Area of Science:

  • Inorganic Chemistry
  • Crystallography
  • Materials Science

Background:

  • Gold complexes are investigated for their diverse chemical properties and potential applications.
  • Dithiocarbamate ligands offer unique coordination behavior with metal ions.

Purpose of the Study:

  • To elucidate the crystal structure of a new gold(III) dithiocarbamate complex.
  • To analyze the coordination geometry and intermolecular interactions within the crystal lattice.

Main Methods:

  • Single crystal X-ray diffraction was employed to determine the crystal structure.
  • The crystal structure was solved and refined using standard crystallographic techniques.

Main Results:

  • The complex [Au(C5H10NO2S2)Cl2] crystallizes in the P212121 space group.

Related Experiment Videos

  • The gold atom displays a distorted square planar coordination environment due to the chelating dithiocarbamate ligand.
  • Linear ...S...Au...S... chains are observed along the crystallographic a axis.

    • Conclusions:

    • The crystal structure reveals a unique coordination motif for gold(III) with dithiocarbamate ligands.
    • The observed chain structures may influence the material properties of the complex.