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Updated: Dec 13, 2025

Fabrication of Spatially Confined Complex Oxides
Published on: July 1, 2013
Dynamic single-site polysulfide immobilization in long-range disorder Cu-MOFs
Ju Sun1, Xinxin Lu1, Kuang-Hsu Wu1
1Particles and Catalysis Research Laboratory, School of Chemical Engineering, The University of New South Wales, Sydney, NSW 2052, Australia. da-wei.wang@unsw.edu.au.
Abstract:
The structural transformation of MOFs in a polysulfide electrode process is poorly understood. We report the electrochemical amorphization of Cu3(BTC)2 MOFs in polysulfide electrolyte. We unveil the dynamic single-site polysulfide immobilization at the interconvertible Cu2+/Cu+ cation centres upon polysulfide adsorption and desorption, along with the reversible distortion of the Cu-O square planar unit.
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