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Updated: Dec 13, 2025

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
Published on: January 17, 2020
Chiral Transition Metal Oxides: Synthesis, Chiral Origins, and Perspectives
Yiwen Li1, Xiongbin Wang2,3, Jun Miao3
1School of Materials Science and Engineering, Hubei University, Wuhan, 430062, China.
Abstract:
Transition metal oxides (TMOs) consist of a series of solid materials, exhibiting a wide variety of structures with tunability and versatile physicochemical properties. Such a statement is undeniably true for chiral TMOs since the introduction of chirality brings in not only active optical activities but also geometrical anisotropy due to the symmetry-breaking effect. Although progressive investigations have been made for accurately controlled synthesis and relevant explanations on the chirality origin of such materials, the overall field of chiral TMOs is still in its infancy with adequate space for interdisciplinary communications and development. Herein, therefore, recent advances in both experimental phenomena and theoretical calculations in this area are reviewed, to elucidate the underlying chiral origin with respect to their fabrications process, triggering new insights for further evolution of this field.
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