When nanocellulose meets diffraction grating: freestanding photonic paper with programmable optical coupling

Photonic crystals based on plasmonic or dielectric periodic structures have attracted considerable interest owing to their capabilities to control light-matter interactions with tailored precision. By using a nanocellulose derived chiral liquid crystal as a building block, here we demonstrate a bio-inspired dual photonic structure that contains the combination of microscopic periodic 1D surface grating and nanoscopic helical organization, giving rise to programmable colour mixing and polarization rotation. We show that a variation in the photonic band-gap in the bulk matrix leads to simultaneous control over the reflection and diffraction of light with controllable iridescence.