New Interpretation of X-ray Photoelectron Spectroscopy of Imidazolium Ionic Liquid Electrolytes Based on Ionic...

We reported a new perspective on the correlation between the electronic structure of an ionic liquid (IL)-based electrolyte probed by X-ray photoelectron spectroscopy and the transport properties analyzed by impedance spectroscopy. We highlighted the core level chemical shifts of 1-hexyl-3-methylimidazolium (bis(trifluoromethanesulfonyl)imide) (C₁C₆ImTFSI), 1-hexyl-3-methylimidazolium bis(fluorosulfonyl)imide (C₁C₆ImFSI), and 1-hexyl-2,3-dimethylimidazolium bis(trifluoromethylsulfonyl)imide (C₁C₁C₆ImTFSI) laden with LiTFSI salt and vinylene carbonate (VC) or fluoroethylene carbonate (FEC) with regard to the transport properties of cations and anions. We pointed out based on detailed binding energy shift analyses a clear effect of the anion on the local organization of Li⁺ ions. The significant peak shift in the case of C₁C₆ImTFSI laden with LiTFSI corroborates the formation of [Li(TFSI)₂]^- complexes. On the contrary, the lower amplitude of the binding energy shift of C₁C₆ImFSI for both anion- and cation-related peaks indicates that the electronic distribution around the cation and the anion is not affected when the LiTFSI salt is added, which plays a strong role in the ion dynamics (lower viscosity) of the electrolyte. The X-ray photoelectron spectroscopy (XPS) result supports the preponderant role of imidazolium ionic liquid based on FSI anion to form an electrolyte less prone to form ionic complexes. The methylation of the imidazolium cation contributes to the reduction of the interaction between the C₁C₁C₆Im cation and TFSI anion, while additives VC and FEC contribute to the change of the alkyl configuration in C₁C₆Im cation, leading to the modification of the macroscopic properties of the ILs.