Fourth- and Fifth-Order Virial Coefficients from Weak Coupling to Unitarity

In the current era of precision quantum many-body physics, one of the most scrutinized systems is the unitary limit of the nonrelativistic spin-1/2 Fermi gas, due to its simplicity and relevance for atomic, condensed matter, and nuclear physics. The thermodynamics of this strongly correlated system is determined by universal functions which, at high temperatures, are governed by universal virial coefficients b_{n} that capture the effects of the n-body system on the many-body dynamics. Currently, b_{2} and b_{3} are well understood, but the situation is less clear for b_{4}, and no predictions have been made for b_{5}. To answer these open questions, we implement a nonperturbative analytic approach based on the Trotter-Suzuki factorization of the imaginary-time evolution operator, using progressively finer temporal lattice spacings. By means of these factorizations and automated algebra codes, we obtain the interaction-induced change Δb_{n} from weak coupling to unitarity. At unitarity, we find that Δb_{3}=-0.356(4) in agreement with previous results, Δb_{4}=0.062(2), which is in agreement with all previous theoretical estimates but at odds with experimental determinations, and Δb_{5}=0.078(6), which is a prediction. We show the impact of those answers on the density equation of state and Tan contact, and trace their origin back to their polarized and unpolarized components.