Performance of ultraviolet/persulfate process in degrading artificial sweetener acesulfame

The degradation of the artificial sweetener acesulfame (ACE) was investigated using an ultraviolet (UV)₃₆₅-activated peroxydisulfate (PDS) process. The results demonstrated that the ACE reaction rate with the UV/PDS process followed pseudo first-order kinetics (R² > 0.9) under various conditions. A high dosage of PDS, alkaline condition, and the existence of NO₃^- and Cl^- enhanced ACE degradation; however, a high dosage of ACE, the existence of HCO₃^-, humic acid, and fulvic acid, and a real water matrix did not facilitate the degradation of ACE. Four types of transformation products were detected in the degradation of ACE by UV/PDS, and the primary degradation pathways were oxidation, hydroxyl substitution, hydrolysis, and hydration. The hydroxyl radicals played a predominant role (71.31%) in the degradation of ACE by the UV/PDS process, followed by sulfate radicals (14.57%) and UV photolysis (8.83%). Both the degradation and mineralization rates of ACE using the UV/PDS process had significant advantages over that of the UV/H₂O₂ process regarding ACE degradation, indicating that the UV/PDS process is more promising for treating water containing ACE.