Fluorescent Metallosupramolecular Elastomers for Fast and Ultrasensitive Humidity Sensing

Fluorescent supramolecular polymers that can respond to subtle external stimuli to generate luminescence signals are promising in a wide range of applications, including probes, anti-counterfeiting materials, and sensors. However, complicated preparative procedures, limited responsive speed, and relatively low sensitivity still limit their practical sensing applications. Herein, we report europium-containing metallosupramolecular (PU-Eu) elastomers for fast and ultrasensitive humidity sensing by employing hygroscopic polyurethane (PU), whose urethane groups can coordinate with europium ions (Eu³⁺), emitting a strong luminescent signal by ligand-to-metal energy transfer. The variant of the coordination bond strength triggered by external humidity imparts the PU-Eu elastomer with a fast (∼1.1 s) and ultrasensitive response to the humid condition, where the external humidity increases by ∼1% and the corresponding fluorescence intensity will drop by ∼421.98 a.u. By a dip-coating process, PU-Eu elastomers can be conveniently coated on a hydrophilic and porous cellulose acetate nanofiber membrane, and the resulting composite membrane can achieve real-time and reversible monitoring of environmental humidity and human respiration. Given the versatility of PU-Eu elastomers, this study provides a low-cost and facile route of obtaining fluorescent metallosupramolecular polymers for fast and ultrasensitive humidity sensing.