Related Experiment Video
Updated: Dec 11, 2025

Preparation of SNS CobaltII Pincer Model Complexes of Liver Alcohol Dehydrogenase
Published on: March 19, 2020
Ligand architecture for triangular metal complexes: a high oxidation state Ni3 cluster with proximal metal
Manar M Shoshani1, Theodor Agapie1
1Department of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA. agapie@caltech.edu.
Abstract:
A new multidentate tetraanionic ligand platform for supporting trinuclear transition metal clusters has been developed. Two trisphenoxide phosphinimide ligands bind three Ni centers in a triangular arrangement. The phosphinimide donors bridge in μ3 fashion and the phenoxides complete a pseudo-square planar coordination sphere around each metal center. Electrochemical studies reveal two pseudo-reversible oxidation events at notably low potentials (-0.80 V and +0.05 V). The one electron oxidized species was characterized structurally, and it is assigned as a NiIII-containing cluster.
More Related Videos
16:11Thermochemical Studies of NiII and ZnII Ternary Complexes Using Ion Mobility-Mass Spectrometry
Published on: June 8, 2022
11:04Ion Mobility-Mass Spectrometry Techniques for Determining the Structure and Mechanisms of Metal Ion Recognition and Redox Activity of Metal Binding Oligopeptides
Published on: September 7, 2019
Related Concept Videos
Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Valence Bond Theory
Coordination Number and Geometry
Complexation Equilibria: Factors Influencing Stability of Complexes
Ladder Diagrams: Complexation Equilibria
The formation constant, K1, for the formation of Cd(NH3)2+ complex from cadmium and ammonia is 3.55 × 102. Log K1 (i.e. pNH3) is 2.55, and...
Coordination Compounds and Nomenclature