Intervening Bismuth Tungstate with DNA Chain Assemblies: A Perception toward Feedstock Conversion via...

An advanced approach with DNA-mediated bismuth tungstate (Bi₂WO₆) one-dimensional (1-D) nanochain assemblies for hydrogen production with 5-fold enhanced photoelectrochemical (PEC) water splitting reaction is presented. The creation of new surface states upon DNA modification mediates the electron transfer in a facile manner for a better PEC process. The UV-Vis-DRS analysis results a red shift in the optical absorption phenomenon with the interference of DNA modification on Bi₂WO₆, and, thus, the band gap was tuned from 3.05 eV to 2.71 eV. The applied bias photon-to-current efficiency (ABPE) was calculated and shows a maximum for the Bi₂WO₆@DNA-2 (25.22 × 10^-4%), compared to pristine Bi₂WO₆ (7.76 × 10^-4%). Furthermore, the idea of practical utility of produced hydrogen from PEC is established for the first time with photocatalytic feedstock conversion to platform chemicals using cinnamaldehyde, 2-hydroxy-1-phenylethanone, and 2-(3-methoxyphenoxy)-1-phenylethanone in large scale by hydrogenation and/or hydrogenolysis reactions under eco-friendly green conditions with external hydrogen pressure in an aqueous mixture. Also, the recyclability experiment delivered good yields, which further confirm the robustness of the developed catalyst.