Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Correction: Silina et al. Influence of the Synthesis Scheme of Nanocrystalline Cerium Oxide and Its Concentration on the Biological Activity of Cells Providing Wound Regeneration. <i>Int. J. Mol. Sci.</i> 2023, <i>24</i>, 14501.

International journal of molecular sciences·2026
Same author

Potential of (NH<sub>4</sub>)<sub>2</sub>Ce(PO<sub>4</sub>)<sub>2</sub>·H<sub>2</sub>O Phase for the Next Generation of Sunscreens: UV-Shielding Properties, Cytotoxicity and Biochemical Behavior.

ACS applied bio materials·2026
Same author

Novel ruthenium(II) hexachloromacrobicyclic complexes and their first polyaromatic-terminated diaminoclathrochelate derivative: preparation, structure, redox and adsorption characteristics, and electrocatalytic activity in the hydrogen evolution reaction.

Dalton transactions (Cambridge, England : 2003)·2026
Same author

UV-shielding photochromic composite films based on nanocrystalline cellulose modified with CeO<sub>2</sub> and WO<sub>3</sub> nanoparticles.

Scientific reports·2025
Same author

Design, Characterization, and Enhanced Performance of Electrospun Chitosan-Based Nanocomposites Reinforced with Halloysite Nanotubes and Cerium Oxide Nanoparticles for Wound Healing Applications.

International journal of molecular sciences·2025
Same author

Correction: Sozarukova et al. Gadolinium Doping Modulates the Enzyme-like Activity and Radical-Scavenging Properties of CeO<sub>2</sub> Nanoparticles. <i>Nanomaterials</i> 2024, <i>14,</i> 769.

Nanomaterials (Basel, Switzerland)·2025

Related Experiment Video

Updated: Dec 8, 2025

Application of a Coupling Agent to Improve the Dielectric Properties of Polymer-Based Nanocomposites
06:34

Application of a Coupling Agent to Improve the Dielectric Properties of Polymer-Based Nanocomposites

Published on: September 19, 2020

6.2K

Electrorheological Properties of Polydimethylsiloxane/TiO2-Based Composite Elastomers.

Alexander V Agafonov1, Anton S Kraev1, Alexander E Baranchikov2

  • 1Krestov Institute of Solution Chemistry, Russian Academy of Sciences, 153045 Ivanovo, Russia.

Polymers
|September 23, 2020
PubMed
Summary

Vulcanizing electrorheological elastomers in an electric field enhances their sensitivity but reduces crosslinking. This finding is crucial for designing advanced electroactive elastomeric materials.

Keywords:
TiO2crosslinkingnanomaterialssmart materialsstimuli-responsive materials

More Related Videos

Synthesis of Soft Polysiloxane-urea Elastomers for Intraocular Lens Application
11:49

Synthesis of Soft Polysiloxane-urea Elastomers for Intraocular Lens Application

Published on: March 8, 2019

13.0K
Preparation of Monodomain Liquid Crystal Elastomers and Liquid Crystal Elastomer Nanocomposites
12:21

Preparation of Monodomain Liquid Crystal Elastomers and Liquid Crystal Elastomer Nanocomposites

Published on: February 6, 2016

13.2K

Related Experiment Videos

Last Updated: Dec 8, 2025

Application of a Coupling Agent to Improve the Dielectric Properties of Polymer-Based Nanocomposites
06:34

Application of a Coupling Agent to Improve the Dielectric Properties of Polymer-Based Nanocomposites

Published on: September 19, 2020

6.2K
Synthesis of Soft Polysiloxane-urea Elastomers for Intraocular Lens Application
11:49

Synthesis of Soft Polysiloxane-urea Elastomers for Intraocular Lens Application

Published on: March 8, 2019

13.0K
Preparation of Monodomain Liquid Crystal Elastomers and Liquid Crystal Elastomer Nanocomposites
12:21

Preparation of Monodomain Liquid Crystal Elastomers and Liquid Crystal Elastomer Nanocomposites

Published on: February 6, 2016

13.2K

Area of Science:

  • Materials Science
  • Polymer Science
  • Nanotechnology

Background:

  • Electrorheological elastomers (EREs) are smart materials that change properties under an electric field.
  • Polydimethylsiloxane (PDMS) and titanium dioxide (TiO2) nanoparticles are key components in EREs.
  • Understanding the Payne effect is crucial for ERE performance.

Purpose of the Study:

  • To investigate the effect of electric field-assisted vulcanization on the properties of PDMS-based EREs filled with TiO2 nanoparticles.
  • To compare the viscoelastic and dielectric properties of EREs vulcanized with and without an electric field.
  • To analyze the influence of the electric field on the Payne effect in these EREs.

Main Methods:

  • Synthesis of PDMS-based EREs filled with hydrated TiO2 nanoparticles (100-200 nm).
  • Vulcanization of the elastomeric matrix in the presence and absence of an external electric field.
  • Characterization of viscoelastic properties (storage modulus, loss modulus) and dielectric properties.
  • Analysis of the Payne effect and degree of crosslinking.

Main Results:

  • EREs vulcanized in an electric field exhibited significantly enhanced electrorheological sensitivity (250% for storage modulus, 1100% for loss modulus).
  • The electric field during vulcanization was found to decrease the degree of crosslinking in the elastomer.
  • The study revealed the influence of the electric field on the Payne effect in EREs.

Conclusions:

  • Vulcanization of TiO2-filled PDMS elastomers in an electric field is a viable method to boost electrorheological sensitivity.
  • A reduced degree of crosslinking is a key consequence of electric field-assisted vulcanization, impacting material design.
  • These findings provide critical insights for the rational design of novel electroactive elastomeric materials.