Facile construction of large-area periodic Ag-Au composite nanostructure and its reliable SERS performance

With the maturity of nano-manufacturing technology, nano-materials with excellent surface-enhanced Raman scattering (SERS) activities have evolved from homogeneous materials to composite ones, but the structural uniformity of composite materials has not been effectively improved. We successfully obtained a series of Ag-Au composite nanostructures with high SERS activity by using a two-step deposition and confined spheroidization process and one-step in-situ substitution method. Anodized alumina templates with uniform size distribution were employed as the initial confined template for spheroidizing Ag film into periodic Ag nanoparticles (Ag NPs). The composite nanostructure was simply obtained after a one-step in-situ galvanic reaction based on the Ag NPs arrays. The results showed that the prepared Ag-Au composite nanostructure could be used as reliable SERS substrates with low relative standard deviation value of ∼6.25% for crystal violet molecules. Compared with previous reports, this one-step route greatly simplifies the process of preparing periodic composite nanomaterials and provides a new idea for constructing multi-component metal nanostructures.