Green Wastes Mediated Zinc Oxide Nanoparticles: Synthesis, Characterization and Electrochemical Studies

Zinc Oxide (ZnO) nanoparticles were prepared using a simple green synthesis approach in an alkaline medium, from three different extracts of citrus peels waste. The synthesized nano-crystalline materials were characterized by using ultraviolet-visible spectroscopy (UV-vis), x-ray powder diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), energy-dispersive x-ray spectroscopy (EDS), environmental scanning electron microscopy (ESEM), and transmission electron microscopy (TEM). UV-vis analysis of the nanoparticles showed broad peaks around 360 nm for the ZnO NPs (Zinc oxide nanoparticles) from three citrus peels' extracts. ZnO NPs exhibited Zn-O band close to 553 cm^-1, which further verified the formation of the ZnO NPs. A bandgap of 3.26 eV, 3.20 eV and 3.30 eV was calculated for the ZnO NPs from grape (ZnO NPs/GPE), lemon (ZnO NPs/LPE), and orange (ZnO NPs/OPE) peels extract, respectively. The average grain sizes of the ZnO nanoparticles were evaluated to be 30.28 nm, 21.98 nm, and 18.49 nm for grape (ZnO NPs/GPE), lemon (ZnO NPs/LPE), and orange (ZnO NPs/OPE) peel extract, respectively. The surface morphology and sizes of the nanoparticle were confirmed by ESEM and TEM analysis, respectively. Furthermore, the zeta potential of the as-prepared ZnO NPs from OPE, LPE, and GPE was -34.2 mV, -38.8 mV, and -42.9 mV, respectively, indicating the high stability of the nanoparticles. Cyclic voltammetric properties of the synthesized nanoparticles were investigated across extracts, and the results showed that the citrus peels extracts (CPE) mediated ZnO NPs modified screen plate carbon (SPC/ ZnO NPs/CPE) electrodes exhibited enhanced catalytic properties when compared with the bare SPCE. The electroactive areas computed from the enhancement of the bare SPCE was approximately three times for SPCE/ ZnO NPs/LPE, and SPCE/ZnO NPs/GPE, and two times for SPCE/ZnO NPs/OPE, higher than that of the bare SPCE. Comparison across the extracts suggested that the catalytic properties of the nanoparticles were unique in ZnO NPs from GPE.