Photocatalytic CO₂ Reduction and Electrocatalytic H₂ Evolution over Pt(0,II,IV)-Loaded Oxidized Ti Sheets

Energy recycling and production using abundant atmospheric CO₂ and H₂O have increasingly attracted attention for solving energy and environmental problems. Herein, Pt-loaded Ti sheets were prepared by sputter-deposition and Pt⁴⁺-reduction methods, and their catalytic activities on both photocatalytic CO₂ reduction and electrochemical hydrogen evolution were fully demonstrated. The surface chemical states were completely examined by X-ray photoelectron spectroscopy before and after CO₂ reduction. Gas chromatography confirmed that CO, CH₄, and CH₃OH were commonly produced as CO₂ reduction products with total yields up to 87.3, 26.9, and 88.0 μmol/mol, respectively for 700 °C-annealed Ti under UVC irradiation for 13 h. Pt-loading commonly negated the CO₂ reduction yields, but CH₄ selectivity was increased. Electrochemical hydrogen evolution reaction (HER) activity showed the highest activity for sputter-deposited Pt on 400 °C-annealed Ti with a HER current density of 10.5 mA/cm² at -0.5 V (vs. Ag/AgCl). The activities of CO₂ reduction and HER were found to be significantly dependent on both the nature of Ti support and the oxidation states (0,II,IV) of overlayer Pt. The present result could provide valuable information for designing efficient Pt/Ti-based CO₂ recycle photocatalysts and electrochemical hydrogen production catalysts.