Behavior of Zinc Incorporation into Fuel Deposits in Borated and Lithiated Water with Dissolved Zinc

The objective of this study was to investigate the behavior of zinc incorporation into newly forming fuel deposits and pre-formed deposits in a simulated pressurized water reactor coolant including 1000 ppm of boron and 2 ppm of lithium at 328 °C. Zinc was incorporated into fuel deposits that were being newly nucleated and grown on nuclear fuel cladding tubes in a zinc-containing coolant. The zinc incorporation resulted in a decrease in the lattice constant of the deposits, which was attributed to the decrease in larger iron content and the corresponding incorporation of smaller zinc in the deposits. However, zinc incorporation was not found, even after the fuel deposits pre-formed before zinc addition were subsequently exposed to the 60 ppb of zinc coolant for 500 h.