NiO_x nanoparticles obtained from hydrothermally treated NiC₂O₄ as an electron blocking layer for organic...

A room-temperature p-type NiO_x film synthesized from a NiC₂O₄ precursor via hydrothermal treatment is employed as an electron blocking layer (EBL) to fabricate organic photodetectors (OPDs). A simple and efficient calcine process at 375 °C in air decomposes the NiC₂O₄ particles into NiO_x, removes organic components and crystal water, and releases CO₂ gas. Our experimental results indicate that this gaseous by-product prevents the agglomeration of NiO_x, which yields smaller nanoparticles (5-10 nm). The formation of an EBL at room temperature improves device performance. After optimization, the performance parameters obtained, including dark current density, responsivity, specific detectivity and response, are 1.13 × 10^-7 A cm^-2, 0.74 A W^-1, 3.86 × 10¹² Jones, and 0.5/8 ms, respectively. Additionally, the dark current is reduced by more than an order of magnitude after the insertion of the NiO_x layer. The proposed simple and easy method for producing an EBL could be beneficial for the commercial low-temperature and large-area preparation of OPDs.