Enhanced luminescence through interface energy transfer in hierarchical heterogeneous nanocomposites and application...

Highly efficient light-emitting materials are essential for achieving high-performance devices. Here, a novel composite system, as well as enhanced luminescence processes, was designed, where NaLn(MoO₄)₂ ultra-small nucleus can be effectively isolated by In(OH)₃ to form NaLn(MoO₄)₂@In(OH)₃ composite nanoclusters due to the different nucleation rate between NaLn(MoO₄)₂ and In(OH)₃, and then these small composite clusters gradually self-assemble into hierarchical structures. As we expected, the enhanced luminescence was achieved from hierarchical NaLn(MoO₄)₂ nanostructures with adjusting the distance among NaLn(MoO₄)₂ ultra-small nucleus by inserting In(OH)₃. A series of spectroscopy results show that the In(OH)₃ not only acts as an energy transfer bridge from CTB Eu³⁺ → O^2- (or MoO₄^2- absorption) to Eu³⁺, but also can effectively alleviate the concentration quenching of Ln³⁺ and change the J-O parameters. The Raman peak at 134 cm^-1 is helpful to populate the ⁵D₀ level of Eu³⁺ or the excited states of Er³⁺, resulting in stronger up/down-conversion emissions. The use of NaLn(MoO₄)₂@In(OH)₃ in white light-emitting diodes (LEDs) has been demonstrated. The combination of red emission from NaLn(MoO₄)₂@In(OH)₃ with blue, green, and yellow emission from halide perovskites could achieve white light with excellent vision performance (an LER of 376 lm/W) and superior color quality (CRI > 92). The findings of this experiment provide a new idea for the design of composite interface materials.