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Updated: Aug 19, 2026

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
Published on: April 22, 2016
Single-atom catalysts boost radical-mediated organic synthesis
Meiqi Zhu1, Dingyi Wang1,2, Zezhao Li1
1Department of Chemistry, Northeastern University, Shenyang 110819, China. liwenhao@mail.neu.edu.cn.
None:
Radical-mediated organic synthesis offers mild and sustainable routes to complex molecules, but conventional metal catalysts often suffer from limited activity, selectivity and recyclability. Single-atom catalysts, featuring atomically dispersed metal centres and well-defined coordination environments, provide an efficient platform for single-electron transfer, radical generation and intermediate stabilisation. This review summarises recent advances in single-atom-catalysed radical transformations, with emphasis on catalyst design, characterisation and mechanistic insight, and outlines key challenges and opportunities for developing sustainable radical methodologies based on single-atom catalysis.
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