Chiral Templating of Polycarbonate Membranes by Pinene Using the Modified Atomic Layer Deposition Approach

In this article, chiral templating of a polycarbonate (PC) membrane by (-)-α-pinene using the atomic layer deposition (ALD) approach is investigated. The templating with the enantiomer of (-)-α-pinene, used as a case compound, was performed either on the original commercial PC membrane or on the PC membrane with a beforehand deposited Al₂O₃ layer. The efficiency of the templating was assessed by a difference in the membrane ability to adsorb/absorb (-)-α-pinene, (+)-α-pinene, and their racemic mixture, using a very sensitive gas sorption analyzer. The results clearly show that the solution-diffusion mechanism rather than the sieving mechanism applied for adsorption/absorption of (-/+)-α-pinene enantiomers, which have the same size of the molecule. The PC membrane with the predeposited Al₂O₃ before the (-)-α-pinene templating shows significantly higher sorption of (-)-α-pinene compared to (+)-α-pinene and racemate, which clearly demonstrates the presence of a chiral recognition effect.