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Updated: Dec 5, 2025

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
Published on: September 8, 2013
Convenient two step synthesis of 29Si labelled tetraalkoxysilanes
Robert Gericke1, Christoph Gondek1, André Stapf1
1Technische Universität Bergakademie Freiberg, Department of Chemistry and Physics, Institute of Inorganic Chemistry, Leipziger Straße 29, 09599 Freiberg, Germany.
Abstract:
29Si enrichment would be advantageous for many NMR studies of the structural properties of sol-gel derived materials. The required starting materials (29Si enriched alkoxysilanes), however, are expensive and difficult to provide. Here we present a scalable, reliable synthesis of 29Si enriched tetraethoxysilane starting from silicon dioxide or elemental silicon with a total yield up to 75%.
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