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Updated: Dec 5, 2025

Time-resolved Photophysical Characterization of Triplet-harvesting Organic Compounds at an Oxygen-free Environment Using an iCCD Camera
Published on: December 27, 2018
Color- and Dimension-Tunable Light-Harvesting Organic Charge-Transfer Alloys for Controllable Photon-Transport
Xixi Han1, Yilong Lei1, Qing Liao2
1Department of Chemistry, School of Science, Tianjin University, Tianjin, 300072, P. R. China.
Abstract:
An electron donor/acceptor pair comprising perylene (Pe) and 9,10-dicyanoanthracene (DCA) was specifically designed to construct organic charge-transfer (CT) alloys via weak CT interaction through a solution co-assembly route. By adjusting the molar ratio between Pe and DCA, we achieve color- and dimension-tunable CT alloy assemblies involving one-dimensional (1D) (DCA)1-x (Pe)x (0 ≤ x ≤10 %) microribbons and two-dimensional (2D) (Pe)1-y (DCA)y (0 ≤ y ≤5 %) nanosheets as a consequence of energy transfer from DCA or α-Pe to Pe-DCA CT complex. Importantly, dimension-related optical waveguiding performances are also revealed: continuously adjustable optical loss in 1D (DCA)1-x (Pe)x microribbons and successive conversion from isotropic waveguide to anisotropic waveguide in 2D (Pe)1-y (DCA)y nanosheets. The present work provides a desired platform for in-depth investigation of light-harvesting organic CT alloy assemblies, which show promising applications in miniaturized optoelectronic devices.
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