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Corannulene Chalcogenides.

Viktor Barát¹, Mihaiela C Stuparu¹

¹Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University Singapore, 21-Nanyang Link, 637371, Singapore.

Chemistry, an Asian Journal

|October 21, 2020

Summary

Incorporating sulfur, selenium, and tellurium into corannulene structures creates novel molecular materials. These chalcogen-modified corannulenes offer tunable properties for advanced applications.

Keywords:

chalcogens corannulene fused-ring systems seleniumtellurium

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Area of Science:

Materials Science
Organic Chemistry
Supramolecular Chemistry

Background:

Polycyclic aromatic hydrocarbons (PAHs) are tunable via heteroatom incorporation.
Corannulene, a fullerene fragment, serves as a versatile scaffold for functional materials.
Chalcogen (sulfur, selenium, tellurium) derivatives of PAHs represent an emerging class of responsive materials.

Purpose of the Study:

To review the synthesis and properties of chalcogen-containing corannulene derivatives.
To highlight the impact of chalcogen incorporation on corannulene's electronic and structural characteristics.
To discuss the potential of these modified materials in various applications.

Main Methods:

Literature review of synthetic methodologies for chalcogen corannulenes.
Analysis of reported spectroscopic and structural data.
Discussion of structure-property relationships.

Main Results:

Established synthetic routes exist for sulfur, selenium, and tellurium corannulene derivatives.
Chalcogen incorporation significantly alters electronic properties and molecular geometry.
These derivatives exhibit unique photophysical and self-assembly behaviors.

Conclusions:

Chalcogen-modified corannulenes are promising functional molecular materials.
Further research into their synthesis and applications is warranted.
These materials offer a platform for developing responsive and advanced molecular systems.