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Template-assisted 2D self-assembled chiral Kagomé network for selective adsorption of coronene
Yi Wang1, Xiaoping Tan2, Peng Pang1
1College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, People's Republic of China. msxrmiao@scut.edu.cn wldeng@scut.edu.cn.
Abstract:
Solvent molecules (n-tridecane and n-tetradecane) act as templates by coadsorption to direct the assembly of asymmetric 2-bisthienyl-4,6-diamino-1,3,5-triazine into chiral Kagomé networks. Furthermore, guest molecules (coronene) fill in the hexagonal voids by replacing the solvent molecules due to the selective and competitive adsorption behavior.
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