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A Critical Review on the Properties and Applications of Sulfur-Based Concrete

Roman Fediuk1, Y H Mugahed Amran2,3, Mohammad Ali Mosaberpanah4

  • 1Department of Hydraulic Engineering and the Theory of Constructions, Far Eastern Federal University, 690091 Vladivostok, Russia.

Materials (Basel, Switzerland)
|October 27, 2020
PubMed

Keywords:
binderfresh propertieshardened propertiesmeltmodifiersulfursulfur-based concrete

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Sulfate attack on concrete is a deterioration process characterized by a whitish discoloration beginning at the edges and corners, accompanied by cracking and spalling. This phenomenon occurs when sulfates react with the components of hardened concrete, forming compounds like calcium sulfate and calcium sulfoaluminate which occupy more space than the substances they replace, causing the concrete to expand and disrupt.
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When acids come into contact with concrete, they initiate a chemical reaction that dissolves the hydrated cement paste. This process leads to softening and structural weakening of the concrete. This issue is commonly observed in environments such as chimneys, sewers, and industrial settings. The severity of the damage increases as the pH of the water interacting with the concrete drops below 6.5. In particular, a pH under 4.5 can cause significant concrete damage.
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Concrete exposed to seawater can undergo degradation like the dissolution of ettringite and gypsum, increasing the material's porosity and decreasing its strength. In contrast, the crystallization of salts within the concrete's pores can cause expansion, particularly above the waterline where evaporation occurs. Nonetheless, this expansion only happens when seawater, enabled by the concrete's permeability, manages to infiltrate the structure.
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Concrete is a vital construction material extensively used worldwide, primarily valued for its strength, durability, and versatility, which it provides for various structural designs. Concrete generally comprises ingredients like Portland cement, coarse gravel, fine sand, and water. Concrete can be mixed by simple hand methods or industrially at computer-controlled plants. The mixture consists of aggregates and a paste made from water and Portland cement. This paste coats the aggregates and,...
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Portland cement comes in several types, each with distinct properties and applications based on their chemical composition and hydration characteristics:
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Portland blast-furnace cement is made by blending Portland cement clinker with granulated blast-furnace slag, which accounts for 25 to 65 percent of the cement's weight. Despite its similarities to ordinary Portland (Type I) cement in terms of fineness and setting times, its early strength is lower, though it achieves comparable strength later on. It's particularly suited for mass concrete structures and marine environments due to its lower heat of hydration and superior sulfate...
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