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REPRODUCIBILITY OF RADON-IN-WATER MEASUREMENTS BY EMANOMETRY TECHNIQUE.

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Quality assurance (QA) procedures for radon in water testing using emanometry were developed and validated. The implemented QA procedures demonstrated effective reproducibility for radon detection in water samples.

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Area of Science:

  • Environmental Science
  • Analytical Chemistry
  • Radiological Protection

Background:

  • Radon in drinking water is a radiological protection concern.
  • Directive 2013/51/Euratom sets strict detection limits for radon in water.
  • The emanometry method is a validated technique for radon detection in water.

Purpose of the Study:

  • To develop and implement quality assurance (QA) procedures for an emanometry-based radon in water measuring system.
  • To evaluate the reproducibility of the QA procedures using multiple identical measurement systems.

Main Methods:

  • Development of QA procedures covering degassing circuit assembly, sample transfer, and control of influencing quantities.
  • Parallel analysis of 39 water samples using three identical emanometry measurement systems.
  • Statistical evaluation of measurement variability to assess QA effectiveness.

Main Results:

  • The developed QA procedures were successfully implemented for the emanometry measuring system.
  • Low variability (<15% for 84% of measurements) was observed among the three systems for radon concentrations in the 10-100 Bq L-1 range.
  • The QA procedures proved effective in ensuring reproducible radon detection in water.

Conclusions:

  • The implemented QA procedures ensure reliable and reproducible radon detection in water using the emanometry method.
  • These QA procedures meet the stringent requirements for radon monitoring in drinking water set by European directives.
  • The study validates the effectiveness of systematic quality control in radiological measurements.