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Single-atom electrocatalysts (SAECs) offer efficient and selective energy conversion. This review summarizes recent advancements in SAECs for key reactions like HER, OER, ORR, CO2RR, and NRR.

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Nanotechnology

Background:

  • Single-atom electrocatalysts (SAECs) are emerging as highly efficient catalysts due to their maximal atomic utilization.
  • Their unique electronic structures offer tunable activity and selectivity for various electrochemical reactions.

Purpose of the Study:

  • To provide a comprehensive review of the recent developments in single-atom electrocatalysts (SAECs).
  • To summarize synthetic strategies, characterization techniques, and applications of SAECs in energy conversion reactions.

Main Methods:

  • Overview of synthetic methodologies for achieving atomic dispersion of metal sites.
  • Discussion of atomically resolved characterization techniques, including advanced microscopy and spectroscopy.
  • Analysis of electrocatalytic performance for hydrogen evolution reaction (HER), oxygen evolution reaction (OER), oxygen reduction reaction (ORR), carbon dioxide reduction reaction (CO2RR), and nitrogen reduction reaction (NRR).

Main Results:

  • Detailed examination of SAECs' catalytic performance, structure-property relationships, and enhancement mechanisms for various reactions.
  • Examples of SAECs are presented, highlighting their effectiveness in HER, OER, ORR, CO2RR, and NRR.

Conclusions:

  • SAECs show significant promise for diverse energy conversion applications.
  • Future perspectives address remaining challenges and opportunities for advancing SAEC development.