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Updated: Dec 2, 2025

Chemical Precipitation Method for the Synthesis of Nb2O5 Modified Bulk Nickel Catalysts with High Specific Surface Area
Published on: February 19, 2018
Synthesis of nickel hexacyanoferrate nanocubes with tuneable dimensions via temperature-controlled Ni2+-citrate
Sascha Keßler1, Guillermo González-Rubio, Elrike Rea Reinalter
1Physical Chemistry, Department of Chemistry, University of Konstanz, Universitätsstrasse 10, D-78457 Konstanz, Germany. Helmut.Cölfen@Uni-Konstanz.de.
Abstract:
The citrate-assisted growth of nickel hexacyanoferrate (NiHCF) nanocubes was investigated. Control over the complexation of Ni2+ ions with citrate at different temperatures enabled fine tuning of the nanocrystal (NC) dimensions and their self-assembly into mesocrystals. Our results introduce new concepts towards the synthesis of NiHCF NCs, potentially applicable to other members of the Prussian blue analogues family.

