Stimulus-responsive luminescent hydrogels: Design and applications

Luminescent hydrogels are emerging soft materials with applications in photoelectric, biomedicine, sensors and actuators, which are fabricated via covalently conjugation of luminophors to hydrogelators or physical loading of luminescent organic/inorganic materials into hydrogel matrices. Due to the intrinsic stimulus-responsiveness for hydrogels such as thermo-, pH, ionic strength, light and redox, luminescent hydrogels could respond to external physical or chemical stimuli through varying the luminescent properties such as colors, fluorescent intensity and so on, affording diverse application potential in addition to the pristine individual hydrogels or luminescent materials. Based on the rapid development of such area, here we systematically summarize and discuss the design protocols, properties as well as the applications of stimulus-responsive luminescent hydrogels. Because of the stimuli-responsiveness, biocompatibility, injectable and controllability of luminescent hydrogels, they are widely used as functional smart materials. We illustrate the applications of luminescent hydrogels. The future developments about luminescent hydrogels are also presented.